You need to troubleshoot your parasitic battery drain before making any changes to the wiring.
Get your multi-meter and set it up for 10 Amp current measurement. Turn the Ignition key to OFF position and remove it for now. Then disconnect the negative wire from the chassis battery and connect your multi-meter in series with the chassis negative wire and battery negative terminal (black wire to battery negative terminal and red wire to ground wire from the engine block).
Check the multi-meter for any current reading. It should be Zero or near zero. You may need to reconfigure your multi-meter to read a lower scale (next scale down is usually about 2 Amps).
If you are reading something well under 100mA, then you likely have parasitic drain from an accessory device like the dash radio or EFI module (if you have that). The OEM wiring for the dash radio is direct from the chassis battery, so I moved my radio power to the House batteries. Under 50mA should not causing any issues. Over 150mA I would look for the cause.
Also look for cellphone chargers, anything plugged into a cigarette outlet. Also look for PO installed devices like a hidden lamp.
Devices with electronic switches have been known to randomly turn ON. We had a new model of commercial two-way radio that was killing batteries. Turns out it would turn ON once the battery voltage dropped below 12V. Works as designed!!
Once you have found and corrected the parasitic drain, then consider moving the starter main power wire direct to the battery. It made a difference in cranking speed for me.